The desulphurization process of steel in ladle furnace with a suitably engineered refining slag is one of the most important refining operations in the steelmaking process. Durgapur Steel Plant (DSP) an integrated steel plant of Steel Authority of India Limited (SAIL) is a foremost producer of long products & the lone manufacturer of Forged ...
WhatsApp: +86 18221755073This stage involves refining the steel to achieve the desired chemical composition and temperature. Techniques like ladle metallurgy and vacuum degassing are used to remove remaining impurities and adjust …
WhatsApp: +86 18221755073Steel - Ladle Metallurgy, Alloying, Refining: The carrying out of metallurgical reactions in the ladle is a common practice in practically all steelmaking shops, because it is cost-efficient to operate the primary furnace …
WhatsApp: +86 18221755073The most popular method of desulfurization is removal of sulfur from molten steel to the basic reducing slag. Basic slag is a slag containing mainly basic oxides: CaO, MgO, MnO, FeO. A typical basic slag consists of 35-60% CaO + MgO, 10-25% FeO, 15-30% SiO 2, 5-20% MnO. Transition of sulfur from steel to slag may be presented by the chemical equation: [S] + …
WhatsApp: +86 18221755073International Journal of Advanced Engineering Technology, 2017. This paper review the generation of slag from an integrated steel plant; focusing on, slag generated in blast furnace during process of iron making and through EAF / BOF during process of steel making .The slag generated from BF and EAF/BOF are having different characteristic.
WhatsApp: +86 18221755073Aluminium-killed medium carbon–manganese-resulphurised microalloyed steels such as the 38MnS6 and 38MnVS6 are popular in automotive forgings. The present study explores the steel-making process, which can improve the product quality. The reactions at the secondary steel-making stages: tapping the steel, ladle alloying, vacuum degassing, post …
WhatsApp: +86 18221755073The target composition is in line with slag used in secondary refining, as a requisite to steel desulfurization and to make possible clean steel production. [ 9, 41 ] Additionally to the thermodynamics requisite aforementioned, in the process temperature (~1600 °C), slag with this composition meets the kinetics requisite too, as it has low ...
WhatsApp: +86 18221755073In the present work, "slag–steel" equilibrium experiments were carried out at 1873 K to determine the effects of C/A ratio (CaO/Al 2 O 3) and the binary basicity (CaO/SiO 2) in Al 2 O 3 –CaO–SiO 2 –MgO(–CaF 2) refining slags on the characteristics of the inclusions and sulfur (S) content in 316L stainless steels.Thermodynamic investigations were performed to …
WhatsApp: +86 18221755073In the secondary refining of molten steel, there are two kinds of refining agents: powder or synthetic slag based on calcium compounds (calcium oxide or calcium carbide), and alloying elements, such as calcium, magnesium, aluminum, silicon and rare earth elements, etc. Adding the refining agent into molten steel can play the role of ...
WhatsApp: +86 18221755073The CaO-Al2O3 is the most important basis of the multicomponent slag in the steel making industry. The microstructure of molten CaO-Al2O3 systems affects the physical, chemical, and metallurgic ...
WhatsApp: +86 18221755073Consistent chemistry of the secondary steelmaking slag. Faster steel refining times during the secondary steelmaking. Sulphur and inclusion removal from the steel making the steel cleaner. Greater yields during the continuous casting through improved castability. A good cover slag for the prevention of gaseous pick-up from the atmosphere.
WhatsApp: +86 18221755073In order to make the refined slag match various grades of spring steel, high-temperature equilibrium experiments were conducted in the laboratory to study the effect of CaO–Al 2 O 3 –SiO 2 –MgO refining slag with varying basicity, Al 2 O 3 content, and CaF 2 additives on inclusions containing Al (Al 2 O 3) in silicon–manganese-deoxidised steel.The …
WhatsApp: +86 18221755073The development of refining slag is the core of the ladle furnace (LF) refining processes and is essential for fast and effective desulfurization refining. Desulfurization reactions are mainly determined by slag–steel interactions, which are closely related to the physicochemical properties of slags. This study reviews the research progress ...
WhatsApp: +86 18221755073Steelmaking slag, or steel slag, is a by-product from the production of steel during the conversion of hot metal to crude steel in a basic oxygen furnace, or during the melting of …
WhatsApp: +86 18221755073Mineral process wastes, such as metallurgical slags nowadays, are of significant metals and materials resources in the circular economy. The usability of iron-making slag is well established; however, steel slag still needs to be utilized due to various physicochemical constraints. In this context, we have reviewed the global steel slag generation, processing, …
WhatsApp: +86 18221755073The most favorable composition for the refining slag is composed of 51–56 mass% CaO, 9–13 mass% SiO2, 20–25 mass% Al2O3 and 6 mass% MgO. In this case, the inclusions in 50CrVA spring steel are mostly in the low melting point regions, in which their plasticities are expected to improve during steel rolling.
WhatsApp: +86 18221755073Steel slag is a byproduct of the steelmaking and steel refining processes. This paper provides an overview of the different types of steel slag that are generated from basic …
WhatsApp: +86 18221755073A process of refining steel in a ladle using solid granules or briquettes made from recycled LMF slag and raw materials to make a desulfurizing addition, a slag conditioner or synthetic refining slag is described. The preferred recycled LMF slag material generally comprises of 35% to about 65% CaO; 10% to about 35% Al 2 O 3 ; 1% to about 10% SiO 2 ; 3% to about 15% MgO; …
WhatsApp: +86 18221755073This volume examines the basic principles, equipment and operating practices involved in steel-making and refining. In this introductory chapter the structure of this volume is briefly described. ... con, phosphorous, sulfur and manganese are transferred to a slag phase. In the EAF steelmaking process the chemical reactions are similar but ...
WhatsApp: +86 18221755073and flux additions to form a slag Sampling–chemical testing 4–15 Steel at 1650°C (3000°F), chemistry and temperature Tapping 4–8 Steel is poured from furnace into a ladle, typical size = 250 tons Pouring slag offat furnace 3–9 Most slag is removed from furnace, in some shops slag is used to coat furnace walls Steelmaking and Refining ...
WhatsApp: +86 18221755073Thermo-Calc's oxide database, TCOX9, is excellently suited to simulate steel-slag-gas phase reactions occurring during steel making and steel refining. However, these reactions never achieve thermodynamic equilibrium in practice, but are limited by heat and mass transfer to and from the reaction zone.
WhatsApp: +86 18221755073to prevent excessive furnace slag carryover, the average quantity of carried-over converter or fur-nace slag is approximately 1% of the steel tapped. This quantity of slag carried over during tapping corresponds to a slag thickness in a 200 tonne ladle of 5.5 ± 3 cm, in general agreement with plant observations.11
WhatsApp: +86 18221755073The effect of pre-melting refining slag containing different contents of Ce 2 O 3 on the absorption and modification of Al 2 O 3 inclusion in an Al-killed steel was investigated through the slag/steel reaction experiment at 1600 °C. It was found that the replacement of 10 wt.% Al 2 O 3 with Ce 2 O 3 for 50 wt.%CaO-33 wt.%Al 2 O 3 –7 wt.%MgO-10 wt.%SiO 2 refining slag …
WhatsApp: +86 18221755073Ladle slag is a byproduct formed during the ladle refining stage of steel making. It is a dusty material that has been considered industrial waste. ... lines of the equilibrium …
WhatsApp: +86 18221755073Argon Oxygen Decarburization Process. satyendra; April 28, 2014; 35 Comments ; AOD converter, CO dilution, decarburization, degassing, Side blown, stainless steel, tuyeres,; Argon Oxygen Decarburization Process. Argon oxygen decarburization (AOD) is a process mainly used in production of stainless steel and other high-grade alloys such as …
WhatsApp: +86 18221755073molten steel is covered with slag formers or an insulating layer after the slag removal. The steel slag produced during the ladle refining stage consists of calcium oxide (CaO) and magnesium oxide (MgO), contributing to 60% of its weight. All the other added alloys and the chemicals used to protect the refractory
WhatsApp: +86 18221755073Steel - Basic Oxygen, Refining, Alloying: More than half the world's steel is produced in the basic oxygen process (BOP), which uses pure oxygen to convert a charge of liquid blast-furnace iron and scrap into steel. The basic oxygen furnace (BOF) is a refractory-lined, tiltable converter into which a vertically movable, water-cooled lance is inserted to blow …
WhatsApp: +86 18221755073furnace, or as they melt in the early stages of formation of steel- making slags. Selection of the chemistry for a slag might be in- ... combination with lime as a primary slag in electroslag refining (Duckworth and Hoyle, 1969). Fluorspar is available in several grades, with the lowest grade often used for steelmaking. When the
WhatsApp: +86 18221755073Steel slag is a byproduct of the steelmaking and steel refining processes. This paper provides an overview of the different types of steel slag that are generated from basic-oxygen-furnace (BOF) steelmaking, electric-arc-furnace (EAF) steelmaking, and ladle-furnace steel refining processes.
WhatsApp: +86 18221755073The spring steel 55SiCrA produced in a domestic steel factory is deoxidized by Si with "100 t EAF-LF-VD-CC". The fluoric content (CaF 2 = 17.41–22.15%) and the binary basicity (R = 1.9–3.0) of applied LF refining slag are high. To avoid environmental pollution caused by fluorine, meanwhile guarantee the speed of melting slag and smelting effect on molten steel, …
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