Gypsum-based binders are generally based on the reaction between calcium sulfate hemihydrate (HH) and water to form calcium sulfate dihydrate (DH). Often gypsum can be used as a raw material to obtain hemihydrate. In this study, the obtained alpha hemihydrate consists of large crystals that have more or less lattice defects according to its ...
WhatsApp: +86 18221755073The phase change of hemihydrate to dihydrate gypsum at different pH was followed by XRD. As shown in Fig. 10, the typical diffraction peak (2-theta = 14.82°, PDF card No. 41-0224) of hemihydrate was outstanding in early hydration time at all pH. It was about 30 min that the peak of hemihydrate disappeared in the reference sample.
WhatsApp: +86 18221755073The morphology of hemihydrate gypsum prepared from dihydrate gypsum contained 15 wt% (a) and 0 (b) of attachment water. ... In spite of several differences between α-HH and β-HH, their unit cells are recognized as identical due to their similar powder diffraction patterns . The cell setting and crystal structure of these two forms of HH have ...
WhatsApp: +86 18221755073The difference between the initial and final setting times also increased, and the fluidity of the gypsum slurry was improved. When the borax dosage reached 0.5%, the flexural strength of ... The phase changes of hemihydrate to dihydrate gypsum at different ...
WhatsApp: +86 18221755073It is still uncertain whether β-hemihydrate and dihydrate gypsum influence the properties, especially the phase conversion, of white calcium aluminate cement (CAC). ... with …
WhatsApp: +86 18221755073All of these forms are manufactured from the mineral gypsum, which is calcium sulfate dihydrate (CaSO 4 · 2H 2 O). The only difference between the model materials and gypsum is the amount of water in the crystal. During the manufacture of model materials, water is driven out of the dihydrate gypsum to form the hemihydrate.
WhatsApp: +86 18221755073The dehydration of gypsum to hemihydrate has been studied for decades because it is an important model reaction for understanding fluid-triggered earthquakes, and due to the global use of plaster ...
WhatsApp: +86 18221755073gypsum (CaSO4 2H2O), hemihydrate gypsum (CaSO4 0.5H2O), and anhydrite (CaSO4) [1–3]. Phosphogypsum (PG) is mainly composed of calcium sulfate dihydrate (DH), which is a byproduct from the wet ...
WhatsApp: +86 18221755073This study explored the production of a medium–low strength α-hemihydrate gypsum (α-HH) from phosphogypsum using an autoclaved method. The influence of slurry concentration, spreading thickness, crystallizing agents, slurry pH, autoclaving temperature, and autoclaving time on the properties of α-HH was investigated. The energy consumption of …
WhatsApp: +86 18221755073chemical name of gypsum is calcium sulfate dihydrate (two molecules of water in chemi-cal combination) and the chemical formula is CaSO 4 •2H 2 O. Gypsum turns into anhydrite ... The slurry form of hemihydrate gypsum plaster may be poured between two adhesive layers to manufacture wallboard, placed into molds, or can be used to ll cracks ...
WhatsApp: +86 18221755073The calcium sulphate dihydrate gypsum (CaSO 4 ·2H 2 O) is the most common sulphate evaporite mineral on our planet 1.Sulphate evaporites play an important role in Earth's sulphur cycle and are ...
WhatsApp: +86 18221755073The dehydration products of gypsum under different temperature and water vapor pressure were investigated by thermodynamic theory. Additionally, the rehydration mechanism of soluble anhydrite was ...
WhatsApp: +86 18221755073The dehydration products of gypsum under different temperature and water vapor pressure were investigated by thermodynamic theory. Additionally, the rehydration mechanism of soluble anhydrite was also studied …
WhatsApp: +86 18221755073thermal analysis in a sample of hemihydrate prepared by calcining gypsum under conditions simulating ... (curve b), this may indicate slight differences between
WhatsApp: +86 18221755073Chapter 12 Gypsum materials DEFINITION. Gypsum (calcium sulphate dihydrate) is a naturally occurring mineral used in dentistry to fabricate models (Figure 12.1a), casts and dies (Figure 12.1b).Calcination is the …
WhatsApp: +86 18221755073The results indicates that H 3 PO 4 accelerated hemihydrate gypsum dissolution and dihydrate gypsum precipitation, which included route I, involving Ca 2+ and SO 4 2-, and route II, ... The differences between Figs. 2 b and 3 b were mainly caused by the different w/b in the two tests (Singh and Middendorf, 2007; ...
WhatsApp: +86 18221755073Flue-gas desulphurization (FGD) gypsum is a highly prevalent industrial by-product worldwide, which can be an excellent alternative to natural gypsum due to its high content of CaSO4·2H2O. The preparation of α …
WhatsApp: +86 18221755073The temperature at which the gypsum binder (calcium sulfate hemihydrate) is industrially produced, between 80 and 180 °C, is often mentioned in the literature [14,15,16,17].However, dehydration from gypsum to basanite (CaSO 4 ·0.5H 2 O) starts at a much lower temperature. The dehydration temperature depends on the measurement method, …
WhatsApp: +86 18221755073According to the difference in hydration, calcium sulfate can be divided into dihydrate gypsum (CaSO4 2H2O), hemihydrate gypsum (CaSO4 0.5H2O), and anhydrite (CaSO4) [1–3]. ... the solubility difference between DH and -HH, thus accelerating the transformation (crystallinity). However, the potential relationship between DH to -HH conversion ...
WhatsApp: +86 18221755073Attribute Gypsum Plaster of Paris; Chemical Formula: CaSO4·2H2O: CaSO4·0.5H2O: Appearance: White or colorless: White or off-white: Hardness: 2 on Mohs scale: 2 on Mohs scale
WhatsApp: +86 18221755073Difference Between Gypsum and Anhydrite. Table of Contents. Key Differences Comparison Chart Compare with Definitions Common Curiosities Share Your Discovery. ADVERTISEMENT. ... Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is widely mined and is used as a fertilizer and as …
WhatsApp: +86 18221755073The most prevalent sulfate mineral in the surrounding natural environment is calcium sulfate, which can be found as calcium sulfate dihydrate or gypsum (CaSO 4 ⋅2H 2 O), hemihydrate (CaSO 4 ⋅ ...
WhatsApp: +86 18221755073Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate. It's found in sedimentary rock formations and is mined. Plaster of Paris, however, is a fine white powder produced by heating gypsum to remove water molecules. ... A hemihydrate gypsum product. Plaster of Paris sets rapidly due to its hemihydrate form. 12. Shumaila Saeed ...
WhatsApp: +86 18221755073Fig. 6 - SEM analysis of hemihydrate gypsum, hemihydrate phosphogypsum, and processed hemihydrate phosphogypsum obtained in the autoclave (a-c) and microwave reactor (d-f).
WhatsApp: +86 18221755073chemical name of gypsum is calcium sulfate dihydrate (two molecules of water in chemi-cal combination) and the chemical formula is CaSO 4 •2H 2 O. Gypsum turns into anhydrite ...
WhatsApp: +86 18221755073Alcohol–water solution-mediated transformation of gypsum into α-hemihydrate (α-HH) whiskers provides a green alternative for the high-value-added recycling of flue gas desulfurization (FGD) gypsum. However, the role of non-lattice cations during the transformation is still unclear. We report an evolution from "boosting–retarding" to "boosting–retarding–boosting" and finally ...
WhatsApp: +86 18221755073Calcium sulfate exists in three forms, namely dihydrate or gypsum (CaSO4·2H2O), anhydrite (CaSO4), and hemihydrate or bassanite (CaSO4·0.5H2O) depending on temperature, pressure, pH, and formation conditions. The formation of calcium sulfates occurs widely in nature and in many engineering settings. Herein, a dataset containing the …
WhatsApp: +86 18221755073Gypsum (calcium sulfate dihydrate) is one of the most used inorganic binding materials in the world. During calcination, calcium sulfate subhydrates are formed and, for technical reasons, are mixed with water to …
WhatsApp: +86 18221755073It was generally supposed the α-hemihydrate CaSO 4 takes shape through a dissolution-recrystallization process. Wu et al. (2011) investigated the direct phase transformation of FGD gypsum to α ...
WhatsApp: +86 18221755073Semantic Scholar extracted view of "Calcium sulphate hemihydrate hydration leading to gypsum crystallization" by N. B. Singh et al. ... of β-hemihydrate to dihydrate (gypsum). The sound velocity is used to quantify the ... X-ray diffraction, optical and electron microscopy techniques. The differences between the two … Expand. 74. Save ...
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